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For some reason, I highly skeptical about the accuracy of your temp. sensor. I think it's highly unlikely to reach a temp of 25C without extraordinary measures although I'm probably wrong?
Also, yes, as CPUs have a higher limit operating temperature, they have lower limit operating temperatures as well. Although, there is no way that a typical user can ever reach those lower limits unless they leave their laptop outside overnight in the middle of winter.
Also, you're going to want to be VERY careful if you try to OC a Sempron because I imagine it's not designed with much flexibility in mind.
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