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That's a file created by the builtin Microsoft Backup. It can only be opened by Backup. I do not recommend you do it this way. The WD external drive should have come with backup software - probably Dantz Retrospect. Install it in Windows and use that.
No need to have separate partitions, clones, NTFS/FAT32 splits. Just format the whole external drive NTFS and let the Dantz software do its thing.
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