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It's a lot easier to use MSN or another IM program to do it - with IRC you have to forward router ports to get DCC through it. I frequently use AIM to send files to people. There is NOTHING that's gonna work over the Internet that's any faster. It's reasonably secure if you are both in front of your computer and initiate the transfer manually, you don't have to expose your upload and download folders to the public at large.
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