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Are you looking to share your internet connection? If so, you will need to get a router(if you have broadband). If you dont get a router then it is based on one pc being the host and the other being a client. Depending on what OS you are running on the computers, there is a program in windows to chat over a lan but you can also get programs that do the same thing with more options. You can choose to share certain folders or drives in windows and set passwords to get access. As for the sharing optical drives over the network, it can be done, i don't know exactly how to do it, but someone here does.
^dan
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