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Careful that you're not using ATI's proprietary MPEG-2 codec! They have one, and it'll be the default option when capturing.
Note that you might have to re-encode your audio as well. MPEG-2 audio isn't valid for NTSC, only PAL. A standalone DVD player will only accept Dolby Digital, MPEG-1, or LPCM for audio on an NTSC DVD.
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