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Before you do anything else, back up your data files onto another drive or removable media, anything you do from here on could possibly make the drives inaccessible and break the mirror permanently.
Remove the drives from the RAID controller and put them one at a time on a standard controller, and see if each one will boot by itself - if each does, try running chkdsk again standalone. I am not basing this recommendation on any hard data, but it's something that I think is logical to try.
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